AISI 4340 Nickel-Chromium-Molybdenum Steel

AISI 4340 is a high-strength, heat-treatable low-alloy steel alloyed with nickel (Ni), chromium (Cr), and molybdenum (Mo). This balanced chemistry delivers exceptional toughness, deep hardenability, high fatigue resistance, and mechanical stability even in large cross-section components.

Among hardenable alloy steels, 4340 is regarded as a premium structural material, often selected when grades such as 4140 or 4130 reach their performance limits.

Chemical Composition

Element%Metallurgical Role
Carbon (C)0.38 – 0.43Strength, hardness
Nickel (Ni)1.65 – 2.00Toughness, fatigue resistance
Chromium (Cr)0.70 – 0.90Hardenability, wear resistance
Molybdenum (Mo)0.20 – 0.30High-temperature strength
Manganese (Mn)0.60 – 0.80Strength, deoxidation
Silicon (Si)0.15 – 0.30Strength, deoxidation
Phosphorus (P)≤ 0.035Controlled impurity
Sulfur (S)≤ 0.040Machinability
Iron (Fe)BalanceBase metal

Microstructure & Metallurgy

• Annealed: Ferrite + pearlite (machinable)
• Normalized: Fine pearlite for uniform strength
• Quenched: Martensitic structure
• Tempered: Tempered martensite (optimal strength–toughness balance)

Nickel enhances impact resistance and fracture toughness, while chromium and molybdenum ensure deep hardening and resistance to thermal softening.

Mechanical Properties

PropertyTypical Range
Tensile Strength745 – 1,860 MPa
Yield Strength470 – 1,500 MPa
Hardness217 – 525 HB
Elongation10 – 25%
Impact ToughnessExcellent (sub-zero capable)
Fatigue ResistanceVery high
Density~7.85 g/cm³
Modulus of Elasticity~205 GPa

Key Characteristics

Exceptional Hardenability
• Uniform hardness in thick sections
• Superior deep-section performance vs 4140

Outstanding Toughness
• Nickel resists brittle fracture
• Reliable under shock and extreme loads

Superior Fatigue Strength
• Excellent for cyclic and torsional loading
• Ideal for rotating machinery

High Strength-to-Weight Ratio
• Enables weight reduction
• Critical for aerospace and high-speed systems

Heat Treatment & Refining

Annealing: 830–860°C – machinability and stress relief
Normalizing: 870–900°C – grain refinement
Quenching: Oil quench from 830–860°C
Tempering: 200–650°C – tailored strength vs toughness

Surface Treatments:
• Nitriding for high surface hardness
• Induction hardening for localized wear resistance
• Selective carburizing for special designs

Machinability & Welding

• Machinability: Good in annealed or normalized condition
• Weldability: Fair – requires 200–300°C preheat and post-weld stress relief
• Forming: Best performed hot

Available Forms

✔ Hot rolled, cold drawn & forged bars
✔ Plates and sheets
✔ Billets and blooms
✔ Forged shafts, rings, and blocks
✔ Wires and rods
✔ Pre-hardened or Q&T components
✔ Precision-machined parts

International Standards & Equivalents

StandardEquivalent
AISI / SAE4340
ASTMA29, A322
DIN34CrNiMo6
EN1.6582
JISSNCM439
BSEN24

Applications

Automotive & Heavy Machinery: Gears, transmission shafts, crankshafts, axles, couplings

Aerospace: Landing gear components, structural parts, high-strength fasteners

Oil & Gas / Energy: Drilling tools, couplings, power transmission shafts

4340 vs 4140

Property41404340
AlloyingCr–MoNi–Cr–Mo
ToughnessGoodExcellent
HardenabilityHighVery High
CostLowerHigher
Thick Section PerformanceModerateSuperior

Advantages

✔ Exceptional toughness and fatigue life
✔ Deep and uniform hardening
✔ Excellent performance under extreme stress
✔ Long service life for critical components

Limitations

⚠ Higher cost than 4140
⚠ Requires controlled welding procedures
⚠ Not corrosion-resistant without protection

AISI 4340 stands out as a premium alloy steel for applications where strength, toughness, fatigue resistance, and reliability are non-negotiable—making it a trusted choice for aerospace, oil & gas, defense, and heavy engineering components.